Catholic Bible Study is all about perspective. There's the Christo-Centric style, the Theological style, the Canonical style, the historical style, the Liturgical style, and many more. Here are a few ways to get started- from reading to web-based learning.

Scripture from Scratch
http://www.americancatholic.org/newsletters/sfs/archive.asp
Biblical Theology Webinar
http://www.jpcatholic.com/admission/biblical_web.php
Catholic Home Study Service - a free resource for Bible Study at home
http://www.amm.org/chss.htm
Agape Catholic Bible Study
http://www.agapebiblestudy.com/index.html
Daily Word of Life
http://www.daily-word-of-life.com/index.html
Daily Gospel
www.dailygospel.org
The Crossroads Initiative Catholic Bible Study
http://www.crossroadsinitiative.com/library_category/38/catholic_bible_study.html
Boston University C21-Online Mini Courses
http://www.bc.edu/schools/stm/c21online/